Rotaxane is an example of a mechanically-interlocked molecular architecture. What this means is that rotaxane is compound that is a combination of molecules that are not connected by bonding but rather by geometry. An analogy, which is explains this is that of a key and a key chain; the keys are not directly attached to the key chain, yet the keys cannot be removed from the chain until the chain is broken. In this case, the blue part of the rotaxane, which is a dumbbell shaped molecule, plays the role of the key while the cyclobis macrocycle is the key chain.
Crystal Structure of Rotaxane with a Cyclobis Macrocycle |
Image depicting the contraction and expansion of the polymer chain in a way that mimics human muscle movement. |
I was truly fascinated at the idea of a synthetic muscle. A nice and informative read. That's what I like.
ReplyDelete-Jonathan Chao